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1 April 2004 The Solvent-initiated Photolysis of Dichloro(2,2′-bipyridine)platinum(II) in Chloroform
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Abstract

Under 254 nm irradiation, [Pt(bpy)Cl2] is converted to [Pt(bpy)Cl4] in a solvent-initiated process. The reaction is very nearly zero order throughout. The rate decreases slightly with increasing starting concentration. These characteristics can be rationalized by a rate law of the form afS, where fS is the fraction of light absorbed by chloroform. The species that reacts with [Pt(bpy)Cl2] is believed to be CCl3OO.

Sharon Whang, Toño Estrada, and Patrick E. Hoggard "The Solvent-initiated Photolysis of Dichloro(2,2′-bipyridine)platinum(II) in Chloroform," Photochemistry and Photobiology 79(4), 356-359, (1 April 2004). https://doi.org/10.1562/2003-12-05-RA.1
Received: 3 December 2003; Accepted: 1 January 2004; Published: 1 April 2004
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