Baugé, S. M. Y., Lavkulich, L. M., Wilson, J. E. and Schreier, H. E. 2014. Comparison of surface properties of synthetic and soil struvite. Can. J. Soil Sci. 94: 169-176. X-ray, Raman and nuclear magnetic resonance (NMR) analyses of intensively managed agricultural soils in southwestern British Columbia reported the presence of the Mg-phosphate mineral, struvite. Soils are heterogeneous, thus analytical techniques based on single minerals require calibration in order to provide reliable results. A synthetic struvite was used to compare the properties of the soil phosphate with struvite. The results confirmed the presence of struvite and possibly additional species of Mg. Time of flight-secondary ion mass spectroscopy (TOF-SIMS) revealed that the surface of struvite, to 2nm depth, is dominated by Mg with other cations, notably Fe and NH₄ that were measured in minor amounts and were associated with the Mg rich surface layer. The results suggest that P is located within the struvite structure. Chemical reactions of struvite and phosphorus chemistry in these soils appear to be governed by the Mg surface layer.