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This study was conducted in order to fight against pollution of the environment. The study concerns river sediment of the Seybouse River in northeastern Algeria. Northeastern Algeria is known for its various industries (steel, fertilizer, metal processing, etc), and the sediment deposited by the Seybouse River, is probably polluted by heavy metals.
For this study, we used two protocols of digestion of sediments, the first, using a mixture of hydrofluoric acid and perchloric acid, and the second, using aqua regia. The comparison of these two protocols will help us to find the best solubilization and thus facilitate the extraction and determination of heavy metals in sediment.
Before determining the concentration of some heavy metals (Fe, Zn, Mn, Sn, Ni, Cr, Pb and Cu), we first analyzed parameters of sediments such as pH and organic matter. We used atomic absorption spectrometry (AAS) to measure these heavy metals. The functional groups characteristic of organic matter and particularly clays were identified by infrared spectroscopy.
The average concentrations of metals exceeded acceptable standards for sediment pollution with heavy metals. Maximum concentrations in mg/kg respectively of the elements studied (Fe, Zn, Mn, Sn, Ni, Cr, Pb and Cu) were, respectively, 2460.20 ± 74.8; 1140.65 ± 38.2; 3.60 ± 1.2; 1.20 ± 0.5; 16.80 ± 2.6; 9.50 ± 3.2; 476.31 ± 21.6 and 145.15 ± 35.2. These results clearly show that the sediments deposited by the Seybouse River are heavily polluted.
In this paper, particle dispersion and spatial distribution in a full scale (5.5 m x 2.4 m x 3.7 m) forced ventilated room are investigated using four different multiphase flow models, including passive scalar model, discrete particle phase model, mixture model and Eulerian model. The main differences between these four models lie in how the particles are modeled. A two layer k-ε turbulence model is used to calculate airflows. Simulated airflow characteristics and particle concentration are compared with corresponding experimental data. The results show that only discrete particle phase model could predict particle concentration distribution close to experimental values and satisfy the published validation criteria (ASTM D5157-97). The reasons for the failure and success of these models in the present case are discussed. Furthermore, the effects of turbulence models of airflows and treatment of boundary conditions on the particle concentration are also investigated.
Eutrophication is a major threat to many coastal ecosystems worldwide. This paper deals with the sediment-water exchange of phosphorus, one of the elements that may stimulate primary production in the aquatic environment. The lack of phosphorus-binding capacity in sediments at low redox-potential is recognized as an important mechanism for eutrophication-related effects in some areas.
Methods
Twelve sediment cores were collected in the Baltic Proper between 61 m and 175 m water depth and a number of phosphorus fractions were analyzed. Integrating the concentrations over the depth profiles, the amounts of mobile phosphorus were estimated in each core.
Results
It was found that sediments below the redox cline in the Baltic Proper contained small amounts of mobile phosphorus. The total amount of mobile phosphorus in the entire Baltic Proper sediments below 65 m water depth was estimated to between 55,000 tonnes and 156,000 tonnes or between less than 10% to around 25% of the phosphate in the system (water plus sediments). This represents the maximum amount of phosphorus that could possibly be released to the water column from these areas. We argue that the most reasonable estimate of the pool of mobile phosphorus in the sediments is the lower number.
Conclusion
The amounts of mobile phosphorus in sediment cores with oxidized surface layers were higher compared with sediment cores with reduced surfaces, indicating that there is a potential phosphorus-binding capacity in sediments below the redox cline if oxic conditions improved. Oxygenation of the Baltic Proper bottom water between 65 m and 100 m could probably remove around 100,000 tonnes of phosphorus from the water column and reduce phosphorus concentrations in the deep water by on average 30 mg/m3, which would possibly be felt also in the surface water.
The effects of winter temperature rises on soil microbial activity, nutrient and salinity in Ningxia Plain were studied in a field experiment using an infrared radiator to raise temperatures. Winter temperature rises led to increases in soil organic matter, available phosphorus, soil pH and total salt content, but decreased the available nitrogen in soil and the activities of soil catalase, urease and phosphatase. With a winter temperature of 0.5 °C-2.0 °C, the activities of soil catalase, urease and phosphatase were respectively decreased by 0.08-1.20 mL g-1, 0.004-0.019 mg g-1, and 0.10-0.25 mg kg-1; soil organic matter was increased by 0.01-0.62 g kg-1, available nitrogen decreased by 2.45-4.66 g kg-1, available phosphorus increased by 2.92-5.74 g kg-1; soil pH increased by 0.42-0.67, and total salt increased by 0.39-0.50 g kg-1. Winter temperature rises decreased soil microbial activity, accelerated the decomposition of soil nutrients, and intensified soil salinization.
Waste resulting from industrial poultry production systems is becoming an increasingly significant environmental problem in the US, threatening both soil and water quality. The goal of this study was to assess the spatial variability and interactions of selected soil properties (physical, chemical, and biochemical), viz., particle size, pH, enzymatic activity, Soil Organic Carbon (SOC), and Total Nitrogen (TN), across an agricultural landscape used for industrial poultry production. The measured soil properties were separated according to biochemical constituents and soil texture based on the first two principal components, accounting for approximately 60% of the variability across the site. These principal components were then used to generate soil surface maps, indicating areas of possible catalytic activity. Surface maps showed possible increases in biochemical activity around areas of stored poultry litter, suggesting the utility of these methods in determining changes to soil management.
Simazine is commonly used to control broadleaf weeds and annual grasses in perennial tree and vine crops because of its relatively low cost and long residual activity. Simazine may be subject to enhanced biodegradation in some areas which can result in decreased herbicide persistence and reduced residual weed control. Laboratory studies were conducted to determine if rapid simazine degradation occurs in California citrus orchards and if degradation rates are correlated with simazine use history. In the Central Valley, simazine degradation curves indicate that simazine degradation rate is more rapid in soils with a simazine use history (adapted) compared to soils with no recent use (non-adapted). In these soils, simazine dissipation was two- to three-fold faster in adapted compared with the non-adapted soils. However, in southern California, simazine dissipation and mineralization were not substantially different among soils with different simazine use histories. Repeated simazine use in California orchards can lead to the development of enhanced microbial degradation of the herbicide. However, soil type and long-term cropping factors can affect persistence and distribution of herbicide-degrading microbial populations in California orchards.
In most watershed-modeling studies, flow is calibrated at one monitoring site, usually at the watershed outlet. Like many arid and semi-arid watersheds, the main reach of the Santa Cruz watershed, located on the Arizona-Mexico border, is discontinuous for most of the year except during large flood events, and therefore the flow characteristics at the outlet do not represent the entire watershed. Calibration is required at multiple locations along the Santa Cruz River to improve model reliability. The objective of this study was to best portray surface water flow in this semi-arid watershed and evaluate the effect of multi-gauge calibration on flow predictions. In this study, the Soil and Water Assessment Tool (SWAT) was calibrated at seven monitoring stations, which improved model performance and increased the reliability of flow predictions, in the Santa Cruz watershed. The most sensitive parameters to affect flow were found to be curve number (CN2), soil evaporation and compensation coefficient (ESCO), threshold water depth in shallow aquifer for return flow to occur (GWQMN), base flow alpha factor (ALPHA_BF), and effective hydraulic conductivity of the soil layer (CH_K2). In comparison, when the model was established with a single calibration at the watershed outlet, flow predictions at other monitoring gauges were inaccurate. This study emphasizes the importance of multi-gauge calibration to develop a reliable watershed model in arid and semi-arid environments. The developed model, with further calibration of water quality parameters will be an integral part of the Santa Cruz Watershed Ecosystem portfolio Model (SCWEPM), an online decision support tool, to assess the impacts of climate change and urban growth in the Santa Cruz watershed.
This paper presents an estimation of the quantity of carbon fixed in trees in a one hectare (ha) plot at the Cerro Pelado-Gamboa Hydrology Tropical Observatory, which is located in the province of Colon, Panama. The estimation of carbon fixed in trees may provide significant information on carbon flux due to water circulation, which may ultimately enable evaluation of the carbon cycle. All trees larger than 10 cm diameter at breast height (DBH) in the plot were investigated. Carbon fixed within these trees was estimated using a parameterized formula. Tree biomass estimations for the plot were 97.21 Mg ha-1. We identified a rare arboreal pear species (Euphorbiaceous) with higher carbon density than other trees in the plot. The presence of this apparently unique species may be due to specific soil characteristics. The method was evaluated by comparing the results with a second study performed in 2011, which resulted in an estimate of net new carbon (biomass) increment (NNCI), which gives 3.88 Mg ha-1 year-1. In general, the estimation of the biomass and associated carbon content found in this investigation are useful comparative data for economic evaluation of tropical forests in terms of capacity to capture carbon.
This study investigates changes in the nature, concentrations, and fluxes of dissolved organic carbon (DOC) in tile drains (aka subsurface drains), overland flow, and stream flow for 6 spring storms in an artificially drained agricultural watershed. For moderate size storms, DOC concentrations are primarily affected by variations in antecedent moisture conditions. Generally, DOC concentrations and aromaticity increase with flow, especially for storms associated with high antecedent moisture conditions. A shift in the source of DOC to the stream and tile drains from low aromaticity DOC at baseflow, to more aromatic DOC during storms was observed. Data indicates that increases in the frequency and intensity of large precipitation events as well as wetter conditions in spring would likely lead not only to an increase in DOC fluxes (simply because of higher discharge) but also to an increase in the amount of DOC exported for every unit of flow.
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